Magneto-optical properties of Europium hexaboride

TL;DR

This study investigates the magneto-optical properties of EuB₆ using electronic structure calculations, revealing features consistent with experiments and emphasizing the importance of Drude correction in modeling.

Contribution

The paper provides a detailed analysis of EuB₆'s magneto-optical spectrum and highlights the necessity of including Drude correction for accurate theoretical predictions.

Findings

Plasma resonance at 0.3 eV in EuB₆

Absorption onset at 1.5 eV due to 4f to 5d transition

Magneto-optical Kerr effect shows significant rotation at specific energies

Abstract

Full potential spin-polarized self-consistent electronic structure calculation s have been performed on LaB$_{6}$, EuB$_{6}$ and YbB$_{6}$ using Linear Muffin- Tin Orbital Method. The electronic structure of EuB$_{6}$ shows a small overlap near the Fermi level. This is in disagreement with the recent ARPES study. The r eflectivity spectrum shows a plasma resonance at about 0.3 eV in EuB$_{6}$. Abso rption starts at about 1.5 eV and it is due to 4$f$ to 5$d$ transition. Both the se features are reflected in the magneto-optical Kerr spectrum. At 0.3 eV, there is a rotation of +8$^{0}$ to -10$^{0}$ and at 1.5 eV, a rotation of about 0.5$^ {0}$ occurs. The reasonable agreement with MOKE experiment implies that the incl usion of Drude correction is absolutely essential for the treatment of EuB$_{6}$ .