Structural transition in NaxCoO2 with x near 0.75 due to Na rearrangement

TL;DR

This study reveals a temperature-dependent structural transition in NaxCoO2 near x=0.75, driven by Na ion rearrangement, affecting its magnetic and transport properties.

Contribution

It identifies a reversible, temperature-induced structural transition at x=0.75 in NaxCoO2 and links it to Na ion positional changes.

Findings

Two distinct crystal structures observed at room temperature.

Transition from high-symmetry to low-symmetry structure around 323 K.

Structural transition influences magnetic and transport properties.

Abstract

We report neutron powder diffraction measurements on a series of NaxCoO2 samples with x near 0.75 which were prepared under different synthesis conditions. Two different crystal structures for the samples are observed at room temperature. The two structures differ primarily by a shift of a large fraction of the Na ions from a high-symmetry position to a lower-symmetry position. Close inspection of the refinement parameters indicates that the presence of either structure depends sensitively on the Na content x, with x = 0.75 as the critical concentration separating the two phases. By raising the temperature to around T = 323 K, the high-symmetry structure can be converted to the lower-symmetry structure. The transition is reversible, but there is significant hysteresis. We discuss the effects of this structural transition on the bulk magnetic and transport properties.