A dilute limit of CeAl$_3$: Emergence of the single-ion Kondo scaling

TL;DR

This study investigates dilute CeAl$_3$ alloys, revealing that single-ion Kondo behavior emerges at very low concentrations with a small Kondo temperature, highlighting the role of intersite interactions in Kondo screening.

Contribution

It demonstrates the emergence of single-ion Kondo scaling in dilute CeAl$_3$ alloys and quantifies the Kondo temperature, showing the influence of intersite interactions.

Findings

Single-ion Kondo behavior observed below x=0.01

Kondo temperature is approximately 0.2 K

Intersite interactions enhance Kondo screening in CeAl$_3$

Abstract

Strongly diluted Ce$_x$La$_{1-x}$Al$_3$ alloys have been studied by the low temperature specific heat in order to elucidate the mechanism that determine their ground state. All alloys with Ce concentrations of $0.0005 \leq x \leq 0.1$ show a $S=1/2$ Kondo behavior. However, the single-ion scaling is observed only below $x=0.01$. The true single-ion Kondo temperature is small, 0.2 K, and is identical to that for dilute CeAl$_2$. It is about 20 times smaller than that for CeAl$_3$, indicating that intersite interactions facilitate Kondo-screening in CeAl$_3$ and concentrated Ce$_x$La$_{1-x}$Al$_3$ alloys.