Phase diagram of the adhesive hard sphere fluid
M. A. Miller, D. Frenkel
TL;DR
This paper investigates the phase behavior of the Baxter adhesive hard sphere fluid using advanced Monte Carlo simulations, providing detailed data on coexistence, equation of state, and percolation, and comparing results with Percus-Yevick theory.
Contribution
It offers new simulation data and analysis techniques for the phase diagram of the adhesive hard sphere fluid, enhancing understanding beyond existing theoretical models.
Findings
Fluid-fluid coexistence curve determined
Parametrized fits for supercritical equation of state provided
Comparison with Percus-Yevick theory conducted
Abstract
The phase behavior of the Baxter adhesive hard sphere fluid has been determined using specialized Monte Carlo simulations. We give a detailed account of the techniques used and present data for the fluid-fluid coexistence curve as well as parametrized fits for the supercritical equation of state and the percolation threshold. These properties are compared with the existing results of Percus-Yevick theory for this system.
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