Water Absorption and High Electric Conductivity in betha-PbO2 and Ag5Pb2O6
D. Djurek, Z. Medunic, M. Paljevic, and A. Tonejc
TL;DR
This study investigates water absorption and electric conductivity in beta-PbO2 and Ag5Pb2O6, revealing significantly enhanced conductivity in hydrated Ag5Pb2O6 compared to pure silver, using infrared spectrometry and conductance measurements.
Contribution
It provides new insights into the water absorption properties and high electric conductivity of beta-PbO2 and Ag5Pb2O6, especially the conductive behavior of hydrated Ag5Pb2O6.
Findings
Hydrated Ag5Pb2O6 shows conductivity at least an order of magnitude higher than pure silver.
Water absorption affects the electrical properties of beta-PbO2 and Ag5Pb2O6.
Infrared spectrometry confirms water incorporation in the compounds.
Abstract
Water absorption in lead peroxide betha-PbO2 and Bystroem-Evers compound Ag2[Ag3Pb2O6] has been investigated by infrared spectrometry and electric conductance measurements. Hydrated Ag5Pb2O6 exhibits, between room temperature and 690 K, electric conductivity, at least, order of magnitude higher than pure silver.
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Taxonomy
TopicsSolid-state spectroscopy and crystallography · Crystal Structures and Properties · X-ray Diffraction in Crystallography