Systems analysis of the phase diagrams of complex structures

TL;DR

This paper analyzes the phase diagrams of complex mixed compounds, focusing on symmetry changes, phase transition sequences, and the effects of electronic and structural factors, supported by theoretical and experimental comparisons.

Contribution

It introduces a phenomenological framework for understanding phase transitions in complex structures, including incommensurate phases and the influence of electronic subsystems.

Findings

Determined space groups of real structures post phase transition

Developed a theory for sequences of phase transitions with incommensurate phases

Compared theoretical predictions with optical, dielectric, and structural data

Abstract

In frameworks of the phenomenological approach we analyze of the phase diagram of mixed compounds. We obtain space groups of symmetry of the real structures as result of phase transition from close-packed degenerate structure. The theory of a sequence of phase transitions with an incommensurate phase is constructed, and influence of an electronic subsystem and distortions on phase transitions is investigated. We investigate of dependence of the temperature interval existence of an incommensurate phase on the electron concentration and the component deformation tensor in doped semiconductors. The comparison of theoretical results with optical, dielectric and structural data is carried out and parameters of thermodynamic potential are determined.