Magnetic and transport anomalies in the compounds, RCuAs2 (R= Pr, Nd, Sm, Gd, Tb, Dy, Ho, and Er)

TL;DR

This study investigates magnetic and transport properties of RCuAs2 compounds with various rare-earth elements, revealing antiferromagnetic order, field-induced transitions, and anomalies in resistivity that challenge existing theoretical models.

Contribution

It provides detailed experimental insights into the magnetic and transport anomalies in RCuAs2 compounds, highlighting deviations from expected scaling and the need for new theoretical explanations.

Findings

All compounds order antiferromagnetically at low temperatures.

Most compounds exhibit field-induced metamagnetic transitions.

Resistivity shows anomalies and minima in the paramagnetic state.

Abstract

The results of dc magnetization, heat capacity, electrical resistivity (rho) and magnetoresistance measurements are reported in detail for the compounds, RCuAs2 for R= Pr, Nd, Sm, Gd, Tb, Dy, Ho, and Er, crystallizing in HfCuSi2-type tetragonal structure, with the aim of bringing out anomalies among 'normal' (that is, other than Ce and Yb) rare-earths. The results establish that all these compounds order antiferromagnetically at low temperatures with deviations from de Gennes scaling. Isothermal magnetization (M) data below respective Neel temperatures (TN) reveal the existence of field-induced metamagnetic-like transitions for most of the compounds (except R= Sm and Gd), whereas in Sm and Gd compounds M varies essentially linearly with magnetic field. With respect to the rho behavior, there appears to be a subtle difference in the temperature dependence beyond 50 K between Sm on the one hand and the rest on the other. In addition, the unexpected rho(T) minimum reported recently for R = Sm, Gd, Tb and Dy in the paramagnetic state (around 20 to 30 K) is essentially absent for R = Ho and Er. The results overall reveal that the normal rare-earths in this series present an interesting situation in magnetism, warranting a new theoretical approach to describe the transport behavior in the paramagnetic state particularly in the vicinity of TN.