Thermodynamics' first law: what information theory tells us
S. Martinez, A. Plastino, B. H. Soffer

TL;DR
This paper offers a more direct theoretical proof of the first law of thermodynamics, challenging traditional reliance on the adiabatic theorem and strengthening its foundational basis through information theory insights.
Contribution
It provides a novel, direct demonstration of the first law of thermodynamics without using the adiabatic theorem, enhancing its theoretical foundation.
Findings
A direct proof of the first law of thermodynamics
Elimination of the need for the adiabatic theorem
Strengthened theoretical foundation of thermodynamics
Abstract
Thermodynamics, and in particular its first law, is of fundamental importance to Science, and therefore of great general interest to all physicists. The first law, although undoubtedly true, and believed by everyone to be true because of its many verified consequences, rests on a rather weak experimental foundation as its path independent aspect has never been directly verified, and rests on a somewhat weak foundation apropos the need for invoking the so-called adiabatic theorem (AT) to prove it from first principles. We provide here a more direct and convincing theoretical demonstration, without the AT and some other usually employed axioms.
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Taxonomy
TopicsComputational Physics and Python Applications · Statistical Mechanics and Entropy · Advanced Thermodynamics and Statistical Mechanics
