High-temperature weak ferromagnetism on the verge of a metallic state: Impact of dilute Sr-doping on BaIrO3

TL;DR

This study investigates how slight Sr-doping in BaIrO3 drastically suppresses its weak ferromagnetism and induces a nonmetal-metal transition, revealing the delicate interplay between lattice structure, magnetism, and electronic properties.

Contribution

It demonstrates that minimal Sr-doping can significantly alter magnetic and electronic states in BaIrO3, highlighting the tunability of these properties through lattice modifications.

Findings

Sr-doping suppresses Curie temperature (Tc) drastically.

Induces a nonmetal-metal transition at high temperatures.

Reveals the instability and tunability of magnetic and transport properties.

Abstract

The 5d-electron based BaIrO3 is a nonmetallic weak ferromagnet with a Curie temperature at Tc=175 K. Its largely extended orbitals generate strong electron-lattice coupling, and magnetism and electronic structure are thus critically linked to the lattice degree of freedom. Here we report results of our transport and magnetic study on slightly Sr doped BaIrO3. It is found that dilute Sr-doping drastically suppresses Tc, and instantaneously leads to a nonmetal-metal transition at high temperatures. All results highlight the instability of the ground state and the subtle relation between magnetic ordering and electron mobility. It is clear that BaIrO3 along with very few other systems represents a class of materials where the magnetic and transport properties can effectively be tuned by slight alterations in lattice parameters.