Dielectric behavior of Copper Tantalum Oxide

TL;DR

This study investigates the dielectric properties of Cu2Ta4O12, revealing high dielectric constants mainly due to extrinsic effects, with intrinsic properties showing moderate dielectric constant and hopping conduction.

Contribution

It provides a detailed analysis of the dielectric behavior of Cu2Ta4O12, clarifying the extrinsic origin of giant dielectric constants and characterizing its intrinsic dielectric and conduction properties.

Findings

Dielectric constant up to 10^5 due to interfacial polarization.

Intrinsic dielectric constant around 100.

Charge transport via hopping conduction of localized carriers.

Abstract

A thorough investigation of the dielectric properties of Cu2Ta4O12, a material crystallizing in a pseudo-cubic, perovskite-derived structure is presented. We measured the dielectric constant and conductivity of single crystals in an exceptionally broad frequency range up to GHz frequencies and at temperatures from 25 - 500 K. The detected dielectric constant is unusually high (reaching values up to 105) and almost constant in a broad frequency and temperature range. Cu2Ta4O12 possesses a crystal structure similar to CaCu3Ti4O12, the compound for which such an unusually high dielectric constant was first observed. An analysis of the results using a simple equivalent circuit and measurements with different types of contact revealed that extrinsic interfacial polarization effects, derived from surface barrier capacitors are the origin of the observed giant dielectric constants. The intrinsic properties of Cu2Ta4O12 are characterized by a (still relatively high) dielectric constant in the order of 100 and by charge transport via hopping conduction of Anderson-localized charge carriers.