Successive superconducting transitions and Anderson localization effect in Ta$_{2}$S$_{2}$C

TL;DR

This study reveals that Ta$_{2}$S$_{2}$C exhibits two successive superconducting transitions and demonstrates Anderson localization effects, with magnetic properties influenced by intra- and inter-grain phases and localized magnetic moments.

Contribution

It provides detailed characterization of the hierarchical superconducting transitions and links Anderson localization to magnetic susceptibility in Ta$_{2}$S$_{2}$C.

Findings

Successive superconducting transitions at 3.61 K and 9.0 K.

Identification of intra- and inter-grain superconductive states.

Magnetic susceptibility influenced by Anderson localization effects.

Abstract

A complex carbide Ta$_{2}$S$_{2}$C consists of van der Waals (vdw)-bonded layers with a stacking sequence $...$ C-Ta-S-vdw-S-Ta-C- $...$ along the c axis. The magnetic properties of this compound have been studied from DC and AC magnetic susceptibility. Ta$_{2}$S$_{2}$C undergoes successive superconducting transitions of a hierachical nature at $T_{cl} = 3.61 \pm 0.01$ K [$H_{c1}^{(l)}(0) = 28 \pm 2$ Oe and $H_{c2}^{(l)}(0) = 7.7 \pm 0.2$ kOe] and $T_{cu} = 9.0 \pm 0.2$ K [$H_{c2}^{(u)}(0) = 6.0 \pm 0.3$ kOe]. The intermediate phase between $T_{cu}$ and $T_{cl}$, where $\delta \chi (= \chi_{FC} - \chi_{ZFC}) \approx 0$, is an intra-grain superconductive state occurring in the Ta-C layers in Ta$_{2}$S$_{2}$C. The low temperature phase below $T_{cl}$, where $\delta \chi$ clearly appears, is an inter-grain superconductive state. The magnetic susceptibility at $H$ well above $H_{c2}^{(l)}(0)$ is described by a sum of a diamagnetic susceptibility and a Curie-like behavior. The latter is due to the localized magnetic moments of conduction electrons associated with the Anderson localization effect, occurring in the 1T-TaS$_{2}$ type structure in Ta$_{2}$S$_{2}$C.