Inhomogeneous Magnetism in La-doped CaMnO3. (II) Mesoscopic Phase Separation due to Lattice-coupled FM Interactions

TL;DR

This study reveals mesoscopic phase separation in La-doped CaMnO3 driven by lattice-coupled ferromagnetic interactions, highlighting the complex interplay between magnetic phases and lattice effects as a function of doping and temperature.

Contribution

It provides a detailed analysis of how lattice-coupled ferromagnetic interactions induce phase separation in Ca(1-x)La(x)MnO3, emphasizing the role of eg electrons and temperature-dependent magnetic interactions.

Findings

Multiple magnetic and crystallographic phases coexist at low temperatures.

Ferromagnetic double-exchange interactions dominate at higher temperatures.

Structural modifications induced by FM interactions influence phase behavior.

Abstract

A detailed investigation of mesoscopic magnetic and crystallographic phase separation in Ca(1-x)La(x)MnO3, 0.00<=x<=0.20, is reported. Neutron powder diffraction and DC-magnetization techniques have been used to isolate the different roles played by electrons doped into the eg level as a function of their concentration x. The presence of multiple low-temperature magnetic and crystallographic phases within individual polycrystalline samples is argued to be an intrinsic feature of the system that follows from the shifting balance between competing FM and AFM interactions as a function of temperature. FM double-exchange interactions associated with doped eg electrons are favored over competing AFM interactions at higher temperatures, and couple more strongly with the lattice via orbital polarization. These FM interactions thereby play a privileged role, even at low eg electron concentrations, by virtue of structural modifications induced above the AFM transition temperatures.