Electronic-vibrational coupling in single-molecule devices

TL;DR

This paper investigates how electronic-vibrational coupling affects electron transport in single-molecule devices, explaining the variability in experimental observations of vibrational harmonics.

Contribution

It provides a theoretical analysis of inelastic and elastic transport, identifying mechanisms that influence the visibility of vibrational harmonics in experiments.

Findings

Higher harmonics are damped by small factors beyond the coupling constant.

Coupling with molecular motion enhances secondary peaks.

Vibrational mode pumping increases harmonic amplitudes.

Abstract

Experiments studying vibrational effects on electronic transport through single molecules have observed several seemingly inconsistent behaviors, ranging from up to 30 harmonics of a vibrational frequency in one experiment, to an absence of higher-harmonic peaks in another. We study the different manifestations of electronic-vibrational coupling in inelastic and elastic electron transport through single molecules. For the case of inelastic transport, higher harmonics are shown to be damped by additional small factors beyond powers of the electron-vibration coupling constant $\lambda$. Two mechanisms greatly increase the size of secondary peaks in inelastic transport: coupling between electron transport and spatial motion of the molecule, and the ``pumping'' of higher vibrational modes of the molecule when vibrational excitations do not completely relax between electron transits.