Charge disproportionation in YNiO$_{3}$ : ESR and susceptibility study

TL;DR

This study investigates the magnetic properties of YNiO₃ across the metal-insulator transition, revealing charge disproportionation and different magnetic regimes through ESR and susceptibility measurements.

Contribution

It provides evidence for charge disproportionation in YNiO₃ and links magnetic behavior to structural and electronic phase changes.

Findings

Susceptibility shows two Curie-Weiss regimes above and below T_MI.

ESR spectrum appears only in the insulator phase, indicating partial Ni ion contribution.

Charge disproportionation of Ni ions explains magnetic and structural observations.

Abstract

We present a study of the magnetic properties of YNiO$_{3}$ in the paramagnetic range, above and below the metal-insulator (MI) transition. The dc susceptibility, $\chi_{dc}$ (measured up to 1000 K) is a decreasing function of T for $T >$150 K (the N\'{e}el temperature) and we observe two different Curie-Weiss regimes corresponding to the metallic and insulator phases. In the metallic phase, this behaviour seems to be associated with the small ionic radius of Y% $^{3+}$. The value of the Curie constant for T$<$ T$_{MI}$ allows us to discard the possibility of Ni$^{3+}$ localization. An electron spin resonance (ESR) spectrum is visible in the insulator phase and only a fraction of the Ni ions contributes to this resonance. We explain the ESR and $\chi _{dc}$ behaviour for T $<$ T$_{MI}$ in terms of charge disproportionation of the type 2Ni$% ^{3+}\to $ Ni$^{2+}$+Ni$^{4+},$ that is compatible with the previously observed structural transition across T$_{MI}$.