Magnon-polaron and Spin-polaron Signatures in the Specific Heat and Electrical Resistivity of $La_{0.6}Y_{0.1}Ca_{0.3}MnO_3$ in Zero Magnetic Field, and the Effect of $Mn-O-Mn$ Bond Environment

TL;DR

This study investigates the signatures of magnon-polaron and spin-polaron excitations in the specific heat and electrical resistivity of La0.6Y0.1Ca0.3MnO3, revealing complex phase transition behaviors influenced by the Mn-O-Mn bond environment.

Contribution

It introduces a Ginzburg-Landau theory for concurrent phase transitions and analyzes the specific heat behavior, highlighting the roles of collective and independent spin scattering mechanisms.

Findings

Magnon-polaron excitations show a T^{3/2} specific heat dependence.

High-temperature specific heat follows a T^{2/3} law related to fractal network structures.

Fisher-Langer relation between specific heat and resistivity derivative is confirmed.

Abstract

$La_{0.6}Y_{0.1}Ca_{0.3}MnO_{3}$, an $ABO_{3}$ perovskite manganite oxide, exhibits a non trivial behavior in the vicinity of the sharp peak found in the resistivity $\rho$ as a function of temperature $T$ in zero magnetic field. The various features seen on $d\rho/dT$ are discussed in terms of competing phase transitions. They are related to the $Mn-O-Mn$ bond environment depending on the content of the $A$ crystallographic site. A Ginzburg-Landau type theory is presented for incorporating concurrent phase transitions. The specific heat $C$ of such a compound is also examined from 50 till 200 K. A log-log analysis indicates different regimes. In the low temperature conducting ferromagnetic phase, a collective magnon signature ($C \simeq T^{3/2}$) is found as for what are called magnon-polaron excitations. A $C \simeq T^{2/3}$ law is found at high temperature and discussed in terms of the fractal dimension of the conducting network of the weakly conducting (so-called insulating) phase and Orbach estimate of the excitation spectral behaviors. The need of considering both independent spin scattering and collective spin scattering is thus emphasized. The report indicates a remarkable agreement for the Fisher-Langer formula, i.e. $C$ $\sim$ $d\rho/dT$ at second order phase transitions. Within the Attfield model, we find an inverse square root relationship between the critical temperature(s) and the total local $Mn-O-Mn$ strain.