Kinetics of the shear banding instability in startup flows

TL;DR

This paper investigates the early development of shear banding in wormlike micelles using a two-fluid model, revealing how coupling with concentration affects the instability's onset, scale, and experimental observations.

Contribution

It provides a linear stability analysis of shear banding onset in startup flows, highlighting the role of concentration coupling and identifying conditions for instability and length scale selection.

Findings

Instability occurs before the homogeneous flow is reached in startup quenches.

Coupling with concentration enhances short-scale instabilities and broadens the unstable region.

Shear banding can be triggered by flow near demixing conditions.

Abstract

Motivated by experiments on wormlike micelles, we study the early stages of the shear banding instability using a two-fluid Johnson-Segalman model. We perform a linear stability analysis for coupled fluctuations in shear rate, micellar strain and concentration about an initially homogeneous state. First we calculate the ``spinodal'' onset of instability in sweeps along the intrinsic constitutive curve. For startup ``quenches'' into the unstable region, the instability usually occurs before the intrinsic constitutive curve can be attained so we analyse the fluctuations with respect to the homogeneous startup flow to find the selected length and time scales at which inhomogeneity first emerges. In the uncoupled limit, fluctuations in shear rate and micellar strain are independent of those in concentration, and are unstable when the intrinsic constitutive curve has negative slope; but no length scale is selected. When coupled to concentration, this instability is enhanced at short length scales; a length scale is selected, as seen experimentally. The unstable region is then broadened. Far from an underlying (zero-shear) demixing instability, the broadening is slight and the instability is still dominated by shear rate and micellar strain. Close to demixing, instability sets in at very low shear rate, where it is demixing triggered by flow.