Electronic properties of the novel 4d metallic oxide SrRhO3
K. Yamaura, Q. Huang, D.P. Young, M. Arai, E. Takayama-Muromachi
TL;DR
This study investigates the electronic properties of the novel 4d metallic oxide SrRhO3, focusing on doping effects and solubility limits, revealing minimal impact on magnetic and electrical behaviors despite chemical compression.
Contribution
It provides new insights into the doping limits and electronic stability of SrRhO3, a recently synthesized 4d perovskite compound.
Findings
Ca doping up to 5.7% causes chemical compression without significant property change.
Ba doping solubility limit is below 20%.
SrRhO3 remains electronically stable despite doping and compression.
Abstract
The novel 4d perovskite compound SrRhO3 was investigated by isovalent doping studies. The solubility limits of Ca and Ba onto Sr-site were below 80% and 20%, respectively. Although SrRhO3 was chemically compressed, approximately 5.7% by the Ca doping, no significant influence was observed on the magnetic and electrical properties.
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