Multiphase segregation and metal-insulator transition in single crystal La(5/8-y)Pr(y)Ca(3/8)MnO3

TL;DR

This study investigates the insulator-metal transition in La(5/8-y)Pr(y)Ca(3/8)MnO3, revealing a percolation process involving ferromagnetic metallic domains and the coexistence of multiple insulating phases, with phase stability affected by x-ray irradiation.

Contribution

It provides new insights into the phase coexistence and transition mechanisms in manganites, emphasizing the role of non-charge-ordered insulating phases and domain growth.

Findings

Resistivity drops sharply at Tmi without charge-ordering anomalies.

Insulating phase persists below charge-ordering temperature, indicating multiple phases.

X-ray irradiation destabilizes the low-temperature phase-separated state.

Abstract

The insulator-metal transition in single crystal La(5/8-y)Pr(y)Ca(3/8)MnO3 with y=0.35 was studied using synchrotron x-ray diffraction, electric resistivity, magnetic susceptibility, and specific heat measurements. Despite the dramatic drop in the resistivity at the insulator-metal transition temperature Tmi, the charge-ordering (CO) peaks exhibit no anomaly at this temperature and continue to grow below Tmi. Our data suggest then, that in addition to the CO phase, another insulating phase is present below Tco. In this picture, the insulator-metal transition is due to the changes within this latter phase. The CO phase does not appear to play a major role in this transition. We propose that a percolation-like insulator-metal transition occurs via the growth of ferromagnetic metallic domains within the parts of the sample that do not exhibit charge ordering. Finally, we find that the low-temperature phase-separated state is unstable against x-ray irradiation, which destroys the CO phase at low temperatures.