A Lattice-Gas Model of Microemulsions
Bruce M. Boghosian (Boston University), Peter V. Coveney (Schlumberger, Cambridge Research), Andrew N. Emerton (Oxford University)

TL;DR
This paper introduces a lattice gas model for simulating the nonequilibrium behavior of microemulsions, allowing for complex interactions and demonstrating correct phenomenology through simulations.
Contribution
It reformulates an existing lattice gas model with a microscopic approach to include complex interactions, enhancing the modeling of microemulsions.
Findings
Model exhibits correct microemulsion phenomenology
Demonstrates the ability to simulate nonequilibrium dynamics
Contrasts with equilibrium and other lattice gas models
Abstract
We develop a lattice gas model for the nonequilibrium dynamics of microemulsions. Our model is based on the immiscible lattice gas of Rothman and Keller, which we reformulate using a microscopic, particulate description so as to permit generalisation to more complicated interactions, and on the prescription of Chan and Liang for introducing such interparticle interactions into lattice gas dynamics. We present the results of simulations to demonstrate that our model exhibits the correct phenomenology, and we contrast it with both equilibrium lattice models of microemulsions, and to other lattice gas models.
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Taxonomy
TopicsTheoretical and Computational Physics · Surfactants and Colloidal Systems · Stochastic processes and statistical mechanics
