# Phytic Acid and Its Derivatives as Valuable Flame Retardants for Polymer Systems: Current State of the Art and Perspectives

**Authors:** Aurelio Bifulco, Giulio Malucelli

PMC · DOI: 10.3390/polym18060671 · Polymers · 2026-03-10

## TL;DR

This paper explores phytic acid and its derivatives as sustainable, effective flame retardants for polymers, highlighting recent advances and future potential.

## Contribution

The paper introduces phytic acid as a novel bio-sourced flame retardant with high phosphorus content and multiple applications.

## Key findings

- Phytic acid is an efficient dehydrating and char-forming agent under heat exposure.
- Combining phytic acid with carbon or nitrogen sources enhances flame-retardant properties.
- Phytic acid derivatives show promise in textiles, polymers, and foams as sustainable alternatives.

## Abstract

Phytic acid (myo-inositol hexakisphosphate) and its salts, including iron, aluminum, sodium, and lanthanum phytate, are perhaps the most recent discovery in the field of bio-sourced flame retardants. Phytic acid can be extracted from sustainable resources, such as beans, cereals, and oilseeds. Its high phosphorus content (28 wt.% based on molecular weight) organized into six phosphate groups justifies the growing interest this biomolecule has attracted over the last decade in various sectors (as a corrosion inhibitor, antioxidant, and anticancer additive, among others). In addition, when exposed to a flame or an irradiative heat flux, phytic acid is a highly efficient dehydrating and char-forming agent. It also contributes to excellent flame-retardant properties when combined with other carbon sources, such as chitosan, or nitrogen-containing additives, including melamine, urea, and polyethyleneimine. This paper reviews the most recent advances in using phytic acid and its derivatives to design effective flame-retardant systems for textiles, bulk polymers, and foams. It also provides perspectives on possible future developments and implementations.

## Linked entities

- **Chemicals:** phytic acid (PubChem CID 890), sodium phytate (PubChem CID 23724990), chitosan (PubChem CID 129662530), melamine (PubChem CID 7955), urea (PubChem CID 1176)

## Full-text entities

- **Chemicals:** Phytic Acid (MESH:D010833), aluminum (MESH:D000535), phosphorus (MESH:D010758), urea (MESH:D014508), nitrogen (MESH:D009584), sodium (MESH:D012964), phosphate (MESH:D010710), iron (MESH:D007501), chitosan (MESH:D048271), melamine (MESH:C011907), lanthanum phytate (-), polymers (MESH:D011108), carbon (MESH:D002244), flame (MESH:C481028)

## Full text

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## Figures

9 figures with captions in the complete paper: https://tomesphere.com/paper/PMC13030606/full.md

## References

179 references — full list in the complete paper: https://tomesphere.com/paper/PMC13030606/full.md

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Source: https://tomesphere.com/paper/PMC13030606