# Elastic Properties and Piezoelectric Energy Harvesting of a Lead-Free Hybrid Perovskite, (DABCO)RbBr3

## TL;DR

This paper studies a lead-free hybrid perovskite's elastic properties and its potential for energy harvesting.

## Contribution

The study reveals the elastic behavior and piezoelectric energy harvesting potential of (DABCO)RbBr3, a lead-free hybrid perovskite.

## Key findings

- The crystal does not amorphize until 2.3 GPa under pressure.
- The material shows favorable piezoelectric energy harvesting performance in a composite film.
- Elastic moduli and Poisson's ratio are calculated using density functional theory.

## Abstract

Mechanical properties of lead-free hybrid perovskites have attracted growing interest because of their significance in future eco-friendly optoelectronic applications. However, there are very limited studies about the intrinsic elastic properties and high-pressure structural evolution of hybrid perovskites, and the fundamental structure–mechanical property relationships are insufficiently understood. Here, we report the elastic behavior of a three-dimensional (3D) hybrid organic–inorganic perovskite, (DABCO)RbBr3 (DABCO = triethylenediammonium), and confirm the processability through processing with chiral metasurfaces and the generation of circular dichroism. Our in situ high-pressure synchrotron X-ray diffraction experiments demonstrate that this crystal does not start to amorphize until 2.3 GPa. Density functional theory calculations reveal that its E, G and v range between 20.73 and 27.93 GPa, 8.21 and 11.62 GPa and 0.18–0.39, respectively. Additionally, due to the low elastic moduli and polar crystal structure, we fabricate a device of (DABCO)RbBr3 composite film, which shows favorable performance for piezoelectric energy harvesting. This work utilizes (DABCO)RbBr3 to open up new avenues for applications in manufacturing and energy harvesting.