# Enhancing Self-Healing Performance of Cement-Based Materials Through Sodium Silicate and SAP Composite Incorporation

**Authors:** Yumei Kang, Rongbao Wu, Yu Qiao, Chang Xu

PMC · DOI: 10.3390/ma19061249 · Materials · 2026-03-21

## TL;DR

This paper introduces a new self-healing method for cement using sodium silicate and SAPs, which improves healing performance by combining chemical and physical repair mechanisms.

## Contribution

The novel contribution is the synergistic use of sodium silicate and SAPs to enhance self-healing in cement-based materials.

## Key findings

- At optimal dosage, compressive strength recovery reaches 103.1%.
- Capillary water absorption coefficient decreases by 16.57 × 10−3.
- UPV recovery achieves 95.4% with microstructural evidence of C-S-H gel formation.

## Abstract

Conventional admixture-based self-healing technologies are often limited by inadequate internal water supply and a scarcity of unhydrated gel particles. Therefore, this study proposes a new self-healing method that leverages the synergistic interplay between the chemical repair of sodium silicate and the physical clogging of superabsorbent polymers (SAPs) to overcome the aforementioned limitations. The healing efficiency of cement mortar was assessed through compressive strength recovery, capillary water absorption, and ultrasonic pulse velocity (UPV). Microstructural evolution and healing mechanisms were elucidated using scanning electron microscopy (SEM) and X-ray diffraction (XRD). Results indicate that at an optimal dosage (0.5 wt.% for both admixtures), the healing performance is significantly enhanced: the compressive strength recovery rate reaches 103.1%, the capillary water absorption coefficient decreases by 16.57 × 10−3, and the UPV recovery achieves 95.4%. Microstructural analysis reveals that sodium silicate facilitates the reaction between Ca2+ and SiO32− ions, leading to the in situ precipitation of dense C-S-H gel at the crack interface, thereby enabling chemical repair. In contrast, SAP contributes to physical sealing via a swelling and release mechanism.

## Linked entities

- **Chemicals:** sodium silicate (PubChem CID 23266), Ca2+ (PubChem CID 271)

## Full-text entities

- **Genes:** SH2D1A (SH2 domain containing 1A) [NCBI Gene 4068] {aka DSHP, EBVS, IMD5, LYP, MTCP1, SAP}
- **Chemicals:** water (MESH:D014867), S (MESH:D013455), C (MESH:D002244), H (MESH:D006859), polymers (MESH:D011108), Ca2+ (-), Sodium Silicate (MESH:C005691)

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## Figures

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## References

52 references — full list in the complete paper: https://tomesphere.com/paper/PMC13028321/full.md

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Source: https://tomesphere.com/paper/PMC13028321