PFSA D50-U Proton-Exchange Gel Membrane for Symmetric Supercapacitors

TL;DR

This paper explores a new proton-exchange gel membrane for supercapacitors, showing high performance and stability.

Contribution

The first investigation of PFSA D50-U as a gel-state ionomer electrolyte in symmetric supercapacitors.

Findings

PFSA D50-U forms stable gel structures with low internal resistance.

The membrane exhibits high specific capacitance and excellent cycling stability.

Cation type significantly affects gel swelling and ionic conductivity.

Abstract

Gel polymer electrolytes are key components in next-generation energy storage systems, particularly supercapacitors, due to their high ionic conductivity, mechanical robustness, and operational safety. Ionomer-based gels derived from perfluorosulfonic acid (PFSA) are particularly promising, as their nanophase-segregated morphology enables the formation of three-dimensional ionic clusters capable of absorbing and retaining aqueous electrolytes. In this study, the commercial PFSA D50-U (Thasar S.r.l.) membrane was investigated for the first time as a gel-state ionomer electrolyte and separator in symmetric supercapacitors using coconut shell-derived activated carbon (YP-80F Kuraray Co., Ltd.). The effects of cation type on gel swelling, ionic conductivity, and electrochemical performance were investigated using Na2SO4 and Li2SO4 aqueous electrolytes. The results showed that PFSA D50-U formed stable gel structures, resulting in low internal resistance, high specific capacitance, and excellent long-term cycling stability. These findings demonstrate that PFSA D50-U is a novel proton-exchange gel membrane with strong potential for high-performance symmetric supercapacitors and other gel-based energy storage devices.

Figures