# Synthesis of Iron(II,III) Oxide–Titanium Core–Shell Particles via Magnetron Sputtering for Magnetoactive Elastomers

**Authors:** Cristian Padilha Fontoura, Amanda Poletto Santi, Wellington Vieira de Souza, Mariana Roesch-Ely, Cesar Aguzzoli

PMC · DOI: 10.1021/acsomega.5c10485 · ACS Omega · 2026-03-03

## TL;DR

This paper introduces a new method to create stable, biocompatible magnetic particles for use in soft materials like those used in robotics and biomedical devices.

## Contribution

A novel surface-engineering strategy using magnetron sputtering to synthesize Fe3O4@Ti core–shell particles for improved magnetoactive elastomers.

## Key findings

- Fe3O4@Ti core–shell particles enhance chemical stability and surface compatibility.
- The titanium shell enables better dispersion in PDMS matrices for magnetoactive applications.
- This approach addresses limitations of conventional ferromagnetic fillers like corrosion and biocompatibility.

## Abstract

Magnetoactive elastomers
(MAEs) and magnetorheological
elastomers
(MREs) are widely explored for vibration damping, soft robotics, and
biomimetic applications. Conventional ferromagnetic fillers such as
iron (Fe) and its ferrimagnetic oxides (Fe3O4, Fe2O3) provide effective magnetic actuation
but suffer from low corrosion resistance and limited biocompatibility.
While poly­(dimethylsiloxane) (PDMS) offers excellent biocompatibility,
its integration with bare Fe/Fe3O4 particles
remains challenging. In this work, we present a surface-engineering
strategy to overcome these limitations by synthesizing Fe3O4@Ti core–shell particles via magnetron sputtering.
The titanium shell improves chemical stability and surface compatibility,
enabling better dispersion and performance within the PDMS matrix
for magnetoactive applications.

## Linked entities

- **Chemicals:** Fe (PubChem CID 23925), Fe2O3 (PubChem CID 14833), titanium (PubChem CID 23963)

## Full-text entities

- **Chemicals:** titanium (MESH:D014025), Fe3O4@Ti (-), PDMS (MESH:C013830), Fe (MESH:D007501), Fe2O3 (MESH:C000499)

## Full text

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## Figures

11 figures with captions in the complete paper: https://tomesphere.com/paper/PMC13000593/full.md

## References

33 references — full list in the complete paper: https://tomesphere.com/paper/PMC13000593/full.md

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Source: https://tomesphere.com/paper/PMC13000593