# Study on the Effect of CTBN and h-BN Synergistic Toughening on the Damping Properties of Carbon-Fiber-Reinforced Epoxy Composites

## TL;DR

This study shows how combining CTBN and h-BN improves the damping properties of carbon-fiber-reinforced epoxy composites without compromising their structural performance.

## Contribution

A novel hybrid toughening strategy using CTBN and h-BN is introduced to enhance damping in CFRP composites.

## Key findings

- CTBN and h-BN together increase damping (tan δ_max = 0.468) and broaden the damping window (ΔT_half = 28.6 °C).
- CFRP laminates with the hybrid show improved structural damping (ζ: 0.021 → 0.035; δ: 0.132 → 0.221).
- Damping enhancement is attributed to ductile energy dissipation and interfacial friction from CTBN and h-BN.

## Abstract

Carbon-fiber-reinforced polymer (CFRP) composites possess outstanding specific stiffness and strength but typically exhibit low intrinsic damping, which limits vibration attenuation in lightweight dynamic structures. Herein, a hybrid toughening strategy combining carboxyl-terminated butadiene nitrile rubber (CTBN) and hexagonal boron nitride (h-BN) is developed to enhance the damping of CFRP laminates while preserving cure feasibility and thermomechanical stability. An E51/DICY/accelerator epoxy system (100:6.5:1.2, mass ratio) is used as the baseline matrix. Differential scanning calorimetry shows that both CTBN and h-BN shift the cure peak temperature upward (Tp: 160.6 → 170.3 °C) and reduce the reaction enthalpy (ΔH: 386.5 → 255.1 J/g), indicating dilution/transport effects and altered cure kinetics. Dynamic mechanical analysis (DMA) reveals that CTBN exhibits an optimum damping enhancement at 25 phr (tan δ_max = 0.300), whereas h-BN provides a stronger monotonic increase up to 25 phr (tan δ_max = 0.437). Notably, the CTBN/h-BN hybrid (25/25 phr) delivers a high tan δ_max of 0.468 together with the broadest effective damping window (ΔT_half = 28.6 °C), exceeding 85% of the linear additivity criterion proposed herein. When the materials are transferred into CFRP laminates, free-vibration tests (using the logarithmic decrement method) demonstrate a clear structural damping improvement (ζ: 0.021 → 0.035; δ: 0.132 → 0.221; t1/2: 0.48 → 0.27 s). Overall, the results suggest that the damping enhancement arises from a combination of EPBN-mediated ductile energy dissipation and h-BN-related interfacial/interlayer frictional losses, which can be jointly tuned to balance processability, thermal response, and damping performance in CFRPs.