Upcycling Coir Fiber into Polydopamine-Enabled Adsorbents for Efficient Cu(II)/Cd(II) Removal and Effluent Safety
Shangpeng Liu, Wenji Wang, Dadong Wang, Jian Lu, Yibo Li, Mingchen Lv, Min Sun, Zhen Fan

TL;DR
This paper presents a sustainable method to remove copper and cadmium from water using upcycled coir fiber coated with polydopamine, improving both efficiency and safety.
Contribution
The novel contribution is the development of a polydopamine-coated coir fiber adsorbent with significantly enhanced heavy metal removal and reduced biotoxicity.
Findings
PDA/Coir fiber shows 6.84-fold and 12.86-fold higher adsorption capacities for Cu(II) and Cd(II) compared to pristine coir fiber.
Adsorption follows the Langmuir isotherm and pseudo-second-order kinetic model, indicating monolayer binding and efficient uptake.
The treated solutions show reduced biotoxicity, demonstrating improved effluent safety after metal removal.
Abstract
Heavy metal pollution remains a global environmental challenge, calling for sustainable and low-cost sorbents. Here, we upcycle coir fiber into a bioinspired adsorbent by depositing a polydopamine (PDA) coating (PDA/Coir fiber) for efficient Cu(II) and Cd(II) removal from water while improving effluent safety. Scanning electron microscopy (SEM), Fourier transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS), and thermal gravimetric analysis (TGA) confirm successful PDA functionalization and associated structural changes. Compared with pristine coir fiber, PDA/Coir fiber shows 6.84-fold and 12.86-fold higher adsorption capacities for Cu(II) and Cd(II), respectively. Adsorption is well described by the Langmuir isotherm, indicating monolayer-dominated binding. Kinetic analysis shows that the adsorption of both ions follows the pseudo-second-order model. The fiber also exhibits…
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Taxonomy
TopicsAdsorption and biosorption for pollutant removal · Polymer Surface Interaction Studies · Nanomaterials for catalytic reactions
