Sb-Doped SnO2 Hollow Spheres for Low-Resistance and Highly Selective Xylene Sensors

TL;DR

This paper introduces a new xylene sensor using Sb-doped SnO2 hollow spheres that offer high selectivity and low resistance for efficient air quality monitoring.

Contribution

The study introduces Sb-doped SnO2 hollow spheres as a novel material for low-resistance and highly selective xylene detection.

Findings

2 mol% Sb-doped SnO2 achieved a high xylene response (SX = 24.0) and selectivity (SX/SE = 3.4) at 5 ppm.

Sensor resistance was reduced by ~200-fold compared to pure SnO2, reaching 38.5 kΩ.

The sensor detected xylene at 50 ppb with rapid response times of 4–5 seconds.

Abstract

It is important to be able to detect xylene with high selectivity and low sensor resistance when monitoring indoor and outdoor air quality. In this study, we report the development of Sb-doped SnO2 hollow spheres synthesized via ultrasonic spray pyrolysis for high-performance xylene detection with significantly reduced sensor resistance. The 2 mol% Sb-doped SnO2 sensor exhibited a remarkably high response (SX = 24.0) and selectivity (SX/SE = 3.4) toward 5 ppm xylene at 300 °C. Notably, the sensor resistance in air (Ra) was reduced by ~200-fold compared to that of pure SnO2, reaching a practical level of 38.5 kΩ, which enables cost-effective signal measurement. Furthermore, the 2Sb-SnO2 sensor demonstrated a low detection limit of 50 ppb and rapid response times (4–5 s). These results suggest that Sb doping is a highly effective strategy for engineering low-resistance and highly selective SnO2 gas sensors. This study could pave the way for a practical approach to designing xylene detection systems for indoor air monitoring.

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