Electrochemical and Mechanical Performance of Magnetron-Sputtered AlCrFeVTi High-Entropy Alloy Coatings for Lead-Cooled Fast Reactors
Shahid Ali, Zahid Hussain, Abdalelah H. Balal, Yuefei Jia, Naeem ul Haq Tariq, Aiman Mukhtar, Gang Wang

TL;DR
This study explores a new high-entropy alloy coating that shows strong corrosion resistance and mechanical stability for use in nuclear reactors.
Contribution
The paper introduces a novel AlCrFeVTi high-entropy alloy coating with enhanced electrochemical and mechanical properties for nuclear applications.
Findings
The 1400 nm coating showed a tenfold reduction in corrosion current density in NaCl solution.
The thicker coating exhibited improved passive film stability and charge transfer resistance.
Finite element modeling confirmed uniform stress distribution in the coating.
Abstract
High-entropy amorphous materials are attracting increasing attention due to their excellent corrosion resistance and radiation tolerance in nuclear environments. In this study, novel Al2Cr16Fe50V20Ti12 high-entropy alloy (HEA) coatings with thicknesses of 900 nm and 1400 nm were synthesized via magnetron sputtering and systematically evaluated for their structural, electrochemical, and mechanical performance. X-ray diffraction confirmed the amorphous nature of the coatings, while scanning electron microscopy revealed a denser, defect-free, and more uniform morphology in the thicker coating. Electrochemical testing in a 3.5 wt.% NaCl solution demonstrated a tenfold reduction in corrosion current density and nearly a twofold increase in charge transfer resistance for the 1400 nm coating, attributed to its improved passive film stability. Finite element modeling validated the experimental…
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Taxonomy
TopicsHigh Entropy Alloys Studies · Metallic Glasses and Amorphous Alloys · Hydrogen Storage and Materials
