# Efficient electrocatalytic activity of a Fe-MOF based cathode catalyst in PEMFCs

**Authors:** Susmita SINGH, Tanya NISHAD, Debasmita PAUL, Sumi GANGULY, Soumyabrata GOSWAMI

PMC · DOI: 10.55730/1300-0527.3783 · 2025-08-13

## TL;DR

This paper presents a new iron-based catalyst that could replace expensive platinum in fuel cells, offering a cost-effective solution for efficient energy production.

## Contribution

The study introduces a PGM-free Fe-MOF electrocatalyst with exceptional stability and performance for oxygen reduction in PEMFCs.

## Key findings

- The Fe-MOF electrocatalyst demonstrated exceptional chemical and surface stability.
- The material showed great surface morphology that facilitates the cathodic reaction in PEMFCs.

## Abstract

Advancements in cost-effective and efficient alternative energy sources are critical for socioeconomic development. In this study, Iron-based metal–organic framework (Fe-MOF) electrocatalyst was fabricated using an Fe salt and ligand. Several surface characterization methods, including Fourier Transform-Infrared Spectroscopy (FTIR), Scanning Electron Microscope (SEM), and X-ray diffraction (XRD), were used to characterize the electrocatalyst. Additionally, using Chronoamperometry (CA), Electrochemical Impedance Spectroscopy (EIS), Linear Sweep Voltammetry (LSV), and Cyclic Voltammetry (CV), the electrocatalytic behaviour in a cathodic reaction in PEMFCs is investigated. The study showed the material’s exceptional chemical or surface stability, and great surface morphology of the material that facilitated the cathodic reaction. This study reported the development of a Platinum Group Metal (PGM)-free potential electrocatalyst for oxygen reduction reaction at the cathode in Proton Exchange Membrane Fuel Cells (PEMFCs).

## Full-text entities

- **Genes:** GTF2E1 (general transcription factor IIE subunit 1) [NCBI Gene 2960] {aka FE, TF2E1, TFIIE-A}, DNER (delta/notch like EGF repeat containing) [NCBI Gene 92737] {aka UNQ26, bet}, KAT8 (lysine acetyltransferase 8) [NCBI Gene 84148] {aka LIGOWS, MOF, MYST1, ZC2HC8, hMOF}
- **Chemicals:** NaN3 (MESH:D019810), imidazole (MESH:C029899), water (MESH:D014867), KOH (MESH:C029943), Fe (MESH:D007501), Cu (MESH:D003300), HCl (MESH:D006851), KBr (MESH:C039004), oxides (MESH:D010087), 5-aminoisophthalic acid (MESH:C102688), absolute alcohol (MESH:D000431), 5-Azidoisophthalic acid (MESH:C004801), methanol (MESH:D000432), Platinum (MESH:D010984), Metal (MESH:D008670), Fe2+ (-), oxygen (MESH:D010100), sulfides (MESH:D013440), N (MESH:D009584), MOFs (MESH:D000073396), C (MESH:D002244), NaNO2 (MESH:D012977)

## Figures

11 figures with captions in the complete paper: https://tomesphere.com/paper/PMC12965781/full.md

---
Source: https://tomesphere.com/paper/PMC12965781