# Comparative analysis of polydiphenylamine/MWCNT-COOH composites for supercapacitors: recovered vs. commercial nanotube electrodes

## TL;DR

This paper presents a method to recover and reuse materials from old lithium-ion batteries for making supercapacitors.

## Contribution

The novelty lies in reusing recovered composite materials from spent batteries in new energy storage devices.

## Key findings

- Recovered PDPA/MWCNT-COOH composites showed a capacitance of 136.6 mF cm−2 in symmetric supercapacitors.
- Synthesized PDPA/MWCNT-COOH composites achieved 112.59 mF cm−2, increasing to 145.5 mF cm−2 with higher concentration.

## Abstract

This paper reports a method for separating the constituents of a cathode containing a composite of the type polydiphenylamine (PDPA)/multi-walled carbon nanotube grafted with carboxyl groups (PDPA/MWCNT-COOH-1) as active material in end-of-life rechargeable lithium-ion batteries (RLIB) and their reuse as active materials in the field of other energy storage devices. The materials recovered from lithium battery cathodes are characterized by FTIR spectroscopy, Raman scattering, surface-enhanced Raman scattering (SERS), and X-ray diffraction. The use of the PDPA/MWCNT-COOH-1 composite as active material in the development of new energy storage devices, such as symmetric supercapacitors, is also reported. The performance comparison of the recycled composite material (PDPA/MWCNT-COOH-1 and MWCNT-COOH) with the one synthesized from pure chemical compounds (PDPA/MWCNT-COOH-2) is shown. Values of the capacitance of symmetrical supercapacitors, having as electrode materials the composites of the type of a mixture of PDPA/MWCNT-COOH-1 and MWCNT-COOH, as well as PDPA/MWCNT-COOH-2, are equal to 136.6 mF cm−2 and 112.59 mF cm−2. Increasing the concentration of the PDPA/MWCNT-COOH-2 active material in the electrode mass from 80 wt% to 84 wt% led to variations in the capacitance values of the symmetrical supercapacitors from 112.59 mF cm−2 to 145.5 mF cm−2.

This paper reports a method to separate the components of a cathode made of polydiphenylamine/carboxyl-grafted multi-wall carbon nanotube composite from rechargeable lithium-ion batteries and reuse them as active materials for supercapacitors.