# High-Performance Thermochromic Multilayer Coatings of W‑Doped VO2 Nanoparticles Dispersed in an SiO2 Matrix Prepared on Glass at a Low Temperature

**Authors:** Jaroslav Vlček, Michal Kaufman, Elnaz Mohammadi Nia, Jiří Houška, Jiechao Jiang, Radomír Čerstvý, Stanislav Haviar, Efstathios I. Meletis

PMC · DOI: 10.1021/acsanm.5c05734 · ACS Applied Nano Materials · 2026-02-13

## TL;DR

A new low-temperature method creates high-performance thermochromic coatings for glass that can change transparency with temperature.

## Contribution

A novel thermochromic coating with high performance and low-temperature fabrication is developed for building glass applications.

## Key findings

- The coating has a transition temperature of 33°C with high luminous transmittance in both states.
- The solar energy transmittance modulation reaches 15.3%.
- The coating can be fabricated at 350°C without atmospheric exposure.

## Abstract

We report a high-performance thermochromic VO2-based
coating prepared on standard glass at a low substrate temperature
of 350 °C without opening the vacuum chamber to the atmosphere.
It is formed by four layers of W-doped VO2 nanoparticles
dispersed in the SiO2 matrix. The coating exhibits a transition
temperature of 33 °C with an integral luminous transmittance
of 65.4% (low-temperature state) and 60.1% (high-temperature state),
and a modulation of the solar energy transmittance of 15.3%. Such
a combination of properties, together with the low temperature during
preparation, fulfills the requirements for large-scale implementation
on building glass and has not been reported yet.

## Linked entities

- **Chemicals:** VO2 (PubChem CID 34008), SiO2 (PubChem CID 24261)

## Full-text entities

- **Chemicals:** SiO2 (MESH:D012822), Na (MESH:D012964), AA (-), Si (MESH:D012825), W (MESH:D014414), Ar (MESH:D001128), Soda-Lime (MESH:C004569), O (MESH:D010100), metal (MESH:D008670), T (MESH:D014316), polymer (MESH:D011108), C (MESH:D002244), V (MESH:D014639), Vanadium dioxide (MESH:C581824), PVP (MESH:D011205), l-ascorbic acid (MESH:D001205)
- **Species:** Homo sapiens (human, species) [taxon 9606]

## Full text

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## Figures

10 figures with captions in the complete paper: https://tomesphere.com/paper/PMC12954752/full.md

## References

17 references — full list in the complete paper: https://tomesphere.com/paper/PMC12954752/full.md

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Source: https://tomesphere.com/paper/PMC12954752