# Beating Tunnel Vision: Near-Surface Velocity-Map Imaging

**Authors:** Nitish Pal, Preeti M. Mishra, Paul D. Lane, Matthew L. Costen, Kenneth G. McKendrick, Stuart J. Greaves

PMC · DOI: 10.1021/acs.jpca.5c08379 · The Journal of Physical Chemistry. a · 2026-02-17

## TL;DR

Scientists improved velocity-map imaging to better study gas-surface interactions by reducing measurement limitations.

## Contribution

A new method called near-surface VMI is introduced to overcome angular measurement limitations in gas-surface studies.

## Key findings

- Bringing the surface closer to the ionization laser expands the scattering angular range.
- NS-VMI enables detailed analysis of speed and angular distributions from gas-surface collisions.

## Abstract

We demonstrate a new methodology for applying velocity-map
imaging
(VMI) to the study of gas-surface dynamics that allows direct imaging
of the scattering plane. By bringing the surface near to the ionization
laser inside the VMI electrodes, we demonstrate a route to overcoming
“tunnel vision”, a term used to describe the limited
angular acceptance of measurements taken at too great distance from
where the gas-surface interaction takes place. Using a molecular beam
of NO molecules colliding with a surface of highly oriented pyrolytic
graphite as an exemplar system, we show the correlation between the
laser-surface distance and the accessible scattering angular range.
We demonstrate the capabilities of near-surface VMI (NS-VMI) through
the analysis of speed and angular distributions derived from the images.

## Full-text entities

- **Diseases:** SS (MESH:D010534)
- **Chemicals:** PTFE (MESH:D011138), O+ (MESH:D010100), metal (MESH:D008670), PEEK (MESH:C063834), mica (MESH:C011934), N (MESH:D009584), NO2 (MESH:D009585), Coumarin (MESH:C030123), squalene (MESH:D013185), water (MESH:D014867), Nd (MESH:D009354), PFPE (MESH:C078113), silica (MESH:D012822), He (MESH:D006371), NO (MESH:D009614), BOC (-), squalane (MESH:C019556), I2 (MESH:D007455), OH (MESH:C031356), HF (MESH:D006195), CO2 (MESH:D002245), ATP (MESH:D000255), Gas (MESH:D005708)

## Full text

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## Figures

9 figures with captions in the complete paper: https://tomesphere.com/paper/PMC12951571/full.md

## References

72 references — full list in the complete paper: https://tomesphere.com/paper/PMC12951571/full.md

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Source: https://tomesphere.com/paper/PMC12951571