Detection of Hydraulic Oil-Polluted Soil Using a Low-Cost Electronic Nose with Sample Heating

TL;DR

A low-cost electronic nose can detect soil contaminated with hydraulic oil, offering a cost-effective solution for environmental monitoring.

Contribution

The study introduces a custom-built, low-cost electronic nose with sample heating for detecting soil pollution from hydraulic oil.

Findings

The electronic nose achieved 97% accuracy in detecting soil contamination at room temperature.

Sensor heater temperature modulation improved classification performance compared to other methods.

TGS 2602 was the most effective sensor for detecting biodegradable oil contamination.

Abstract

Monitoring soil contamination from petroleum products is vital for protecting human health and the environment. In forestry, hydraulic oil spills frequently result from leaks in equipment such as harvesters. This study evaluates a custom-built, inexpensive electronic nose, equipped with a Figaro TGS gas sensor array, for discriminating between pristine and contaminated soil samples. Two oil types and three pollution intensities were analyzed. The constructed electronic nose applied two sensor operation modes: (i) response to change of sensor operation condition from clean air to target odors and (ii) response to sensor heater temperature modulation. Classification was performed using Random Forest and Support Vector Machine (SVM) algorithms, and Linear Discriminant Analysis (LDA) was used to explore multidimensional data patterns. The sensor heater temperature modulation mode provided superior classification performance. Measurements at room temperature achieved an accuracy of 97%, clearly outperforming measurements on samples heated to 60 °C (75%). While the system successfully identified biodegradable oil contamination, standard mineral oil was more challenging to detect. Among the sensors tested, TGS 2602 was the most effective. These findings indicate that portable electronic noses can provide a statistically robust and cost-effective tool for assessing the severity of soil pollution.

Figures