# Graded Brittle–Ductile Transition via Laser-Induced Thermal Gradient for Broaching of Z10C13 Steel

**Authors:** Guozhen Liu, Zhen Meng, Junqiang Zheng, Weiguang Liu, Xinghua Wu, Jing Ni, Haohan Zhang

PMC · DOI: 10.3390/mi17020204 · 2026-02-02

## TL;DR

A laser technique is used to modify the surface of Z10C13 steel, enabling efficient and precise broaching with reduced cutting force and improved surface quality.

## Contribution

The novel use of laser defocus gradient modification to induce surface embrittlement in martensitic stainless steel for low-speed precision machining.

## Key findings

- A 50 μm gradient remelting layer with ultrafine grains and high GND density was created.
- Surface hardness increased by 12.95%, cutting force decreased by 34.07%, and surface roughness improved by 63.74%.
- A crack-deflection mechanism prevents subsurface damage propagation, creating a crack-free zone.

## Abstract

This paper presents a breakthrough in activating the skin effect at conventional broaching speeds (1–8 m/min) by using laser defocus gradient modification to induce surface embrittlement in martensitic stainless steel Z10C13. Through controlled defocusing, a 50 μm gradient remelting layer was created, which features ultrafine grains (0.8 μm) and a high-density geometrically necessary dislocation (GND) zone (ρGND = 2.27 μm−3). The quasi-cleavage fracture was triggered via dislocation pinning by non-oriented low-angle grain boundaries (28.4% LAGBs). Multiscale characterization confirms that this microstructural transformation enhances surface hardness by 12.95% (reaching 31.4 HRC), reduces cutting force by 34.07%, and improves surface roughness by 63.74% (Sz = 28.80 μm). Simultaneously, a parallel crack-deflection mechanism restricts subsurface damage propagation, resulting in a crack-free subsurface zone. These results demonstrate the effectiveness of the embrittlement–toughening dichotomy for precision machining of difficult-to-cut materials under low-speed constraints.

## Full-text entities

- **Diseases:** Crack (MESH:D003387), fracture (MESH:D050723), injury to (MESH:D014947), Brittle (MESH:D010013), GND (MESH:D004204)
- **Chemicals:** Fe (MESH:D007501), WC (MESH:C002802), stainless steel (MESH:D013193), metal (MESH:D008670), gold (MESH:D006046), C (MESH:D002244), Co (MESH:D003035), Mn (MESH:D008345), oxide (MESH:D010087), Carbide (-), Cr (MESH:D002857)
- **Species:** Homo sapiens (human, species) [taxon 9606]
- **Cell lines:** -5 — Mus musculus (Mouse), Transformed cell line (CVCL_5U93), Z10C13 — Rattus norvegicus (Rat), Spontaneously immortalized cell line (CVCL_JY50)

## Figures

12 figures with captions in the complete paper: https://tomesphere.com/paper/PMC12943548/full.md

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Source: https://tomesphere.com/paper/PMC12943548