# High-Performance Interfacial Solar Evaporation for Zero Liquid Discharge Treatment of Coal Chemical Concentrated Brine: Principles, Challenges, and Recent Advances

## TL;DR

This paper reviews solar evaporation technology for treating high-salinity wastewater from the coal industry, focusing on its potential for zero liquid discharge.

## Contribution

The paper provides a comprehensive review of recent advances in interfacial solar evaporation for concentrated brine treatment.

## Key findings

- Interfacial solar steam generation offers rapid evaporation and low carbon footprint for brine treatment.
- Recent designs improve solar thermal conversion and reduce heat loss and salt accumulation.
- ISSG shows promise for clean and sustainable treatment of coal chemical concentrated brine.

## Abstract

The rapid expansion of the coal chemical industry has led to a growing demand for effective treatment of high salinity wastewater, particularly the concentrated brine streams targeted for zero liquid discharge (ZLD) management. Conventional treatment technologies face significant challenges under such extreme conditions, underscoring the urgency of developing innovative and energy-efficient alternatives. Interfacial solar steam generation (ISSG) has emerged as a promising approach for concentrated brine treatment owing to its rapid evaporation rates, low carbon footprint, and high solar thermal energy utilization. Nevertheless, the long-term stability of solar evaporators remains limited by photothermal material degradation, excessive heat loss, and salt accumulation—all of which constitute major bottlenecks preventing large-scale implementation of ISSG in ZLD systems. This review first outlines the fundamental principles, advantages, and practical constraints of interfacial solar evaporation. It then highlights recent advances in high-performance solar evaporators featuring broadband light absorption, efficient solar thermal conversion, suppressed heat dissipation, robust anti-salt fouling behavior, and sustained operational durability. These emerging designs substantially improve the feasibility of ISSG and provide promising pathways for the clean, efficient, and sustainable treatment of concentrated brine in the coal chemical industry.