# Material Composition Design for Long-Term Stability of Solid Oxide Fuel Cell Based on Creep Damage and Failure Probability

## TL;DR

This paper studies how the composition of materials in solid oxide fuel cells affects their long-term stability and performance under high temperatures.

## Contribution

The study identifies an optimal Ni content range for minimizing creep damage and improving the long-term stability of SOFC electrodes.

## Key findings

- Increasing Ni volume fraction from 30% to 50% reduces creep damage in SOFCs.
- Ni volume fractions above 60% lead to increased creep damage.
- A Ni content of 50–60% is optimal for long-term SOFC operation.

## Abstract

Electrode degradation represents a primary factor contributing to the performance decay. The composition design of electrode materials directly determines the long-term stability of solid oxide fuel cell (SOFC) under high-temperature service conditions. This paper focuses on the effect of anode and cathode material compositions on the creep damage and failure probability of SOFCs after 50,000 h creep. The results reveal an optimal Ni content range for mechanical integrity. Specifically, increasing the Ni volume fraction from 30% to 50% results in a reduction in the creep damage. In contrast, extending the increase to 60–70% causes a general reversal of this trend, with the creep damage showing an overall increase. The paper concludes that the Ni volume fraction of 50–60% is appropriate to maintain the long-term operation of SOFC. The La0.8Sr0.2MnO3 (LSM) volume fraction with higher electrochemical efficiency can be selected for cathode manufacturing. This study provides a reference for developing long-life SOFC electrode materials.