# Machine Learning-Assisted LIBS Identification of Epoxy Resins in CFRP for Recycling Processes

**Authors:** Dimitris Kanakis, Zaira M. Berdiñas, Konstantinos N. Sioutas, Elena Santamarina, Camilo Prieto, Elias P. Koumoulos

PMC · DOI: 10.3390/ma19040751 · Materials · 2026-02-14

## TL;DR

This paper introduces a method combining laser spectroscopy and machine learning to identify epoxy resins in composite materials for better recycling.

## Contribution

The novel integration of LIBS and ML for accurate epoxy resin classification in CFRP recycling is presented.

## Key findings

- LIBS spectrograms were processed to group materials based on Bisphenol-A epoxy resin.
- A Support Vector Classification model achieved an average accuracy of 0.8317 ± 0.0212 using 5-fold cross validation.

## Abstract

Efficient sorting of resin-based CFRP composites is critical for optimizing composite recycling streams. In this work, a methodology integrating Laser-Induced Breakdown Spectroscopy (LIBS) with Machine Learning (ML)-enhanced classification models to achieve accurate material discrimination is presented. LIBS is employed to identify the chemical composition of individual compounds, producing spectrograms that are subsequently processed to group chemically similar materials based on Epoxy resin (Bisphenol-A). The grouped datasets that contain 4000 peaks and 665 features were sampled to standardize feature dimensionality and cleaned to remove noise. A statistical analysis is then conducted to select the most informative features, followed by dimensionality reduction using Linear Discriminant Analysis (LDA). Finally, classification is performed using a Support Vector Classification (SVC) model, fine-tuned to the processed data to maximize accuracy. With a 5-fold cross validation (CV), the average nested accuracy score is 0.8317 ± 0.0212. This integrated approach demonstrates the potential for advancing automated sorting technologies in composite recycling applications.

## Linked entities

- **Chemicals:** Bisphenol-A (PubChem CID 6623)

## Full-text entities

- **Diseases:** LIBS (MESH:D000092582), injury to (MESH:D014947), LIBS-ML (MESH:D007859)
- **Chemicals:** N (MESH:D009584), C (MESH:D002244), polymer (MESH:D011108), O (MESH:D010100), Bisphenol A (MESH:C006780), Epoxy resin (MESH:D004853), CFRP (-), H (MESH:D006859), CFRP (MESH:C037808)
- **Species:** Homo sapiens (human, species) [taxon 9606]

## Full text

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## Figures

9 figures with captions in the complete paper: https://tomesphere.com/paper/PMC12941392/full.md

## References

24 references — full list in the complete paper: https://tomesphere.com/paper/PMC12941392/full.md

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Source: https://tomesphere.com/paper/PMC12941392