# Natural pH-Sensitive Intelligent Edible Gel-Based Packaging: From Structural Design to Fruit Freshness Monitoring

**Authors:** Tong Zhao, Lulu Wang, Xinyue Wang, Meng Zhang, Xin Zhang, Chen Li, Qian Zhang, Yan Zhao, Lixia Wang

PMC · DOI: 10.3390/gels12020169 · Gels · 2026-02-14

## TL;DR

This paper reviews natural pH-sensitive edible gel packaging that helps monitor fruit freshness while being environmentally friendly.

## Contribution

The paper systematically reviews recent advancements in natural pH-sensitive edible gel-based packaging for fruit freshness monitoring.

## Key findings

- Natural pH-sensitive edible gels can visually track fruit freshness through color changes.
- These gels delay ripening and inhibit microbial growth in various fruits.
- Challenges include improving mechanical strength and scalability for practical use.

## Abstract

The escalating demand for global fruit logistics underscores the urgency of packaging innovations to reconcile preservation efficiency with environmental sustainability, particularly addressing microplastic pollution from conventional plastics and safety hazards posed by synthetic pH-sensitive pigments. Natural pH-sensitive intelligent edible gel-based packaging, which integrates non-toxic indicators into biopolymer gel matrices, offers a viable solution by visually tracking freshness through colorimetric responses to pH fluctuations during storage and transportation. This review systematically synthesizes recent progress in material design, including the development of edible films and coatings, and evaluates the functional mechanisms of natural pH indicators within these systems. Applications across diverse fruit categories demonstrate their efficacy in delaying ripening, inhibiting microbial growth, and signaling quality degradation via dynamic color shifts. Despite enabling real-time, visual freshness monitoring, challenges in mechanical robustness, water resistance, and scalable manufacturing remain. Future advancements should prioritize the integration of multifunctional systems, such as gas conditioning technologies and bioactive components, to enhance practical performance and align with sustainable food preservation objectives, ultimately reducing food waste and elevating consumer safety standards.

## Full-text entities

- **Genes:** Zein [NCBI Gene 732802], Transglutaminase [NCBI Gene 100857012]
- **Diseases:** injury to (MESH:D014947), inflammatory (MESH:D007249), tumor (MESH:D009369), weight loss (MESH:D015431), toxicity (MESH:D064420)
- **Chemicals:** CO2 (MESH:D002245), polyene (MESH:D011090), pelargonidin-3-glucoside (MESH:C078485), free radicals (MESH:D005609), Carotenoids (MESH:D002338), CMC (MESH:D002266), sorbitol (MESH:D013012), E (MESH:D004540), lycopene (MESH:D000077276), ZnO (MESH:D015034), Natamycin (MESH:D010866), water (MESH:D014867), guar gum (MESH:C007894), OH- (MESH:C031356), terpenoid (MESH:D013729), methyl red (MESH:C008492), Polypropylene (MESH:D011126), astaxanthin (MESH:C005948), biopolymers (MESH:D001704), poly (lactic acid) (MESH:C033616), Brilliant Yellow (MESH:C059622), beta-carotene (MESH:D019207), Lipid (MESH:D008055), stearic acid (MESH:C031183), ascorbic acid (MESH:D001205), aglycone (MESH:C458179), Cellulose (MESH:D002482), Polyethylene terephthalate (MESH:D011093), beeswax (MESH:C038228), Hydrogen (MESH:D006859), Anthocyanin (MESH:D000872), bromothymol blue (MESH:D001979), xanthophylls (MESH:D024341), sodium hydroxide (MESH:D012972), hydroxyl (MESH:D017665), ROS (MESH:D017382), aldehyde (MESH:D000447), vegetable oils (MESH:D010938), cyanidin-3-glucoside (MESH:C462279), chlorophyllin (MESH:C007020), anthraquinone (MESH:D000880), magnesium (MESH:D008274), betacyanin (MESH:D050859), Polyethylene (MESH:D020959), flavonoid (MESH:D005419), singlet oxygen (MESH:D026082), amylose (MESH:D000688), Shikonin (MESH:C016101), carbinol (MESH:D000432), Curcumin (MESH:D003474), carnauba wax (MESH:C026344), gold (MESH:D006046), naphthoquinone (MESH:D009285), 1,2-dihydroxyanthraquinone (MESH:C010078), porphyrin (MESH:D011166), C14H8O4 (-), betalamic acid (MESH:C000252), metal (MESH:D008670), chalcone (MESH:D002599), sodium alginate (MESH:D000464)
- **Species:** Curcuma longa (turmeric, species) [taxon 136217], Ocimum basilicum (basil, species) [taxon 39350], Solanum tuberosum (potatoes, species) [taxon 4113], Rhodophyta (red algae, phylum) [taxon 2763], PX clade (clade) [taxon 569578], Oryza sativa (Asian cultivated rice, species) [taxon 4530], Rubroshorea almon (species) [taxon 292004], Vigna radiata (mung bean, species) [taxon 157791], Cajanus cajan (pigeon pea, species) [taxon 3821], Arnebia euchroma (species) [taxon 373122], Centrosema molle (butterfly-pea, species) [taxon 1300970], Daucus carota (carrot, species) [taxon 4039], Manihot esculenta (cassava, species) [taxon 3983], Spinacia oleracea (spinach, species) [taxon 3562], Escherichia coli (E. coli, species) [taxon 562], Malus domestica (apple, species) [taxon 3750], Bacteria Latreille et al. 1825 (Bacteria stick insect, genus) [taxon 629395], Staphylococcus aureus (species) [taxon 1280], Helianthus annuus (common sunflower, species) [taxon 4232], Trigonella foenum-graecum (fenugreek, species) [taxon 78534], Saccharomyces cerevisiae (baker's yeast, species) [taxon 4932], Lactobacillus (genus) [taxon 1578], Homo sapiens (human, species) [taxon 9606], Pyrus communis (pear, species) [taxon 23211], Clitoria ternatea (species) [taxon 43366]

## Full text

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## Figures

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## References

151 references — full list in the complete paper: https://tomesphere.com/paper/PMC12940641/full.md

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Source: https://tomesphere.com/paper/PMC12940641