A Keratin-Waste Derived Multifunctional Gel System: Reusable Activated Carbon/Alginate Microbeads for Simultaneous Dye and Pharmaceutical Adsorption

TL;DR

This paper presents a method to create reusable gel microbeads from yak hair waste that can effectively remove dyes and pharmaceuticals from water.

Contribution

The study introduces a novel approach using keratin waste and activated carbon to create multifunctional adsorbent microbeads.

Findings

AC−Alg0.5U microbeads achieved high adsorption capacities for methylene blue (1038.9 mg/g) and methyl orange (206.2 mg/g).

The microbeads showed excellent adsorption for minocycline hydrochloride (1694.2 mg/g) and followed pseudo-second-order kinetics.

The microbeads retained 75% adsorption capacity after six cycles, indicating reusability.

Abstract

The resource utilization of keratin waste has garnered significant attention, yet the processing of yak hair keratin in underdeveloped regions such as Tibet and Qinghai in China remains challenging. This study addresses these concerns by carbonizing yak hair keratin waste using a steam flash explosion (SFE) technique for 150 s, which is followed by activation with KOH at various ratios and subsequent to produce activated carbon (AC) samples. The AC was then combined with sodium alginate (Alg) at different ratios, pH and applied voltage to yield AC−Alg gel microbeads using an electrospinning method. The characterization of the AC and AC–Alg gel microbeads was conducted using SEM, BET, TG, and FT-IR analysis. In adsorption studies, AC−Alg0.5U gel microbeads prepared with optimized conditions (pH 7, 11 kV, 19 G needle) were used to remove dyes (methylene blue (MB) and methyl orange (MO)) and antibiotic minocycline hydrochloride (MH). Various parameters such as temperature, pH, and adsorbent dose were optimized to obtain the maximum adsorption performance under model concentrations. The experimental results showed that the AC−Alg0.5U gel microbeads can effectively adsorb MB and MO with adsorption capacities of 1038.9 mg/g and 206.2 mg/g, respectively. Moreover, the microbeads had the best adsorption performance for MH (1694.2 mg/g), with the kinetics most accurately represented by the pseudo-second-order kinetic model (R2 = 0.999), and the isotherm followed the Langmuir model (R2 = 0.984). The microbeads maintained a high adsorption capacity of 75% after six cycles. The composite gel microbeads not only utilize yak hair keratin waste but also will be used as durable and favorable adsorbents for the removal of pollutants.

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