# Phenanthrene-like Benzodichalcogenophenes: Synthesis, Electrochemical Behavior and Applications

## TL;DR

This paper reviews the synthesis, electrochemical behavior, and applications of phenanthrene-like benzodichalcogenophenes in materials chemistry.

## Contribution

The paper provides a comprehensive review of isomeric benzodichalcogenophene systems and their tailored properties for functional materials.

## Key findings

- Isomeric benzodichalcogenophenes exhibit diverse structural and electronic properties based on ring orientation.
- Tailored functionalization strategies allow for fine-tuning of their intrinsic properties.
- These systems have applications in optoelectronics, supramolecular chemistry, and biological studies.

## Abstract

Benzodichalcogenophenes represent a valuable class of organic π-conjugated systems that have been investigated in a plethora of cutting-edge applications in the field of materials chemistry. Isomeric benzodifuran (BDF), benzodithiophene (BDT) and benzodiselenophene (BDS) analogs of phenanthrene, in which the two heteroaromatic rings are ortho-fused onto a benzene ring, represent convenient frameworks as functional materials in organic electronics. The orientation of the two condensed heteroaromatic rings with respect to the central benzene ring provides diverse structural isomers, which significantly differ in degrees of curvature, electronic and electrochemical properties. Furthermore, tailored modification and functionalization strategies enable fine-tuning of their intrinsic properties, leading to unique systems. This review offers a comprehensive overview of synthetic methodologies for constructing isomeric BDF, BDT and BDS skeletons, alongside an analysis of their electrochemical properties as influenced by the nature of heteroatoms. Finally, the most relevant applications of these systems, ranging from optoelectronics, supramolecular chemistry, and emerging biological studies, are discussed, providing valuable insights for future research direction.