# Sensitive Montmorillonite Evaporation Detector Based on Montmorillonite Monolayer Nanosheets

## TL;DR

Researchers developed a highly sensitive evaporation detector using montmorillonite nanosheets, which could improve green energy applications.

## Contribution

A low-cost, high-conductivity nanofluidic device using montmorillonite with enhanced evaporation detection sensitivity.

## Key findings

- Exolit OP 550 effectively exfoliates montmorillonite into uniform monolayer nanosheets.
- Li+ modification significantly improves the ionic conductivity of the nanofluidic device.
- The device achieves an evaporation detection sensitivity of 10−12 S s−1.

## Abstract

Two-dimensional (2D) materials open up exciting possibilities for the study of ion transport behavior for green energy. Here, a simple and effective strategy to fabricate high-conductivity nanofluidic channels based on exfoliated montmorillonite (MTM) nanosheets is proposed. The resource-rich and low-cost layered MTM was first exfoliated into monolayer nanosheets using Exolit OP 550. Subsequently, the MTM nanosheets with Exolit OP 550 were assembled into 2D nanofluidic devices by the layer-by-layer self-assembly method. The results show that Exolit OP 550 exfoliates different types of layered MTM into monolayer nanosheets with uniform contrast and integrity. The reconstructed Na-MTM nanofluidic device has the highest ionic conductance. The ionic conductivity of the Na-MTM 2D nanofluidic device was effectively improved after Li+ modification with a higher charge density. After further optimizing the content of Exolit OP 550, the ion conductivity of the MTM nanofluidic device reached 4.66 × 10−4 S cm−1, which is 55.3% higher than the highest known value among the same nanofluidic devices. Interestingly, this nanofluidic device exhibited a very high sensitivity in detecting water evaporation, which can reach 10−12 S s−1 in resolution. This economically viable strategy may advance the study of low-dimensional ion transport properties in new energy coatings and the design of evaporation detectors.