# Synergistic Reinforcement and Multimodal Self-Sensing Properties of Hybrid Fiber-Reinforced Glass Sand ECC at Elevated Temperatures

**Authors:** Lijun Ma, Meng Sun, Mingxuan Sun, Yunlong Zhang, Mo Liu

PMC · DOI: 10.3390/polym18030322 · Polymers · 2026-01-25

## TL;DR

A new type of concrete was developed that resists high temperatures and can monitor its own damage, making it suitable for safer and smarter infrastructure.

## Contribution

A hybrid fiber-reinforced ECC with self-sensing properties and enhanced high-temperature performance is introduced.

## Key findings

- Hybrid fibers reduce spalling and improve compressive strength at high temperatures.
- Carbon fibers enhance thermosensitivity, useful for fire warnings.
- High-temperature exposure increases pressure sensitivity but reduces flexural sensitivity.

## Abstract

To address the susceptibility of traditional concrete to explosive spalling and the lack of in situ damage-monitoring methods at high temperatures, in this study, a novel self-sensing, high-temperature-resistant Engineered Cementitious Composite (ECC) was developed. The matrix contains eco-friendly glass sand reinforced with a hybrid system of polypropylene fibers (PPFs) and carbon fibers (CFs). The evolution of mechanical properties and the multimodal self-sensing characteristics of the ECC were systematically investigated following thermal treatment from 20 °C to 800 °C. The results indicate that the hybrid system exhibits a significant synergistic effect: through PFFs’ pore-forming mechanism, internal vapor pressure is effectively released to mitigate spalling, while CFs provide residual strength compensation. Mechanically, the compressive strength increased by 51.32% (0.9% CF + 1.0% PPF) at 400 °C compared to ambient temperature, attributed to high-temperature-activated secondary hydration. Regarding self-sensing, the composite containing 1.1% CF and 1.5% PPF displayed superior thermosensitivity during heating (resistivity reduction of 49.1%), indicating potential for early fire warnings. Notably, pressure sensitivity was enhanced after high-temperature exposure, with the 0.7% CF + 0.5% PPF group achieving a Fractional Change in Resistivity of 31.1% at 600 °C. Conversely, flexural sensitivity presented a “thermally induced attenuation effect” primarily attributed to high-temperature-induced interfacial weakening. This study confirms that the “pore-formation” mechanism, combined with the reconstruction of the conductive network, governs the material’s macroscopic properties, providing a theoretical basis for green, intelligent, and fire-safe infrastructure.

## Full-text entities

- **Chemicals:** polypropylene (MESH:D011126), CF (MESH:D000077482), PPF (-), carbon (MESH:D002244)

## Full text

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## Figures

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## References

48 references — full list in the complete paper: https://tomesphere.com/paper/PMC12899534/full.md

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Source: https://tomesphere.com/paper/PMC12899534