# Comparisons of Thermo-Oxidative Ageing Performance and Lifespan Evaluation of Grafted Polypropylene and XLPE Cables: Combined Effect of Temperature and Thickness

**Authors:** Wenjia Zhang, Shangshi Huang, Mingti Wang, Juan Li, Wei Wang, Shixun Hu, Jinliang He

PMC · DOI: 10.3390/polym18030386 · Polymers · 2026-01-31

## TL;DR

This study compares the long-term durability of grafted polypropylene and XLPE cables under heat and oxidation, showing PPG has a longer estimated lifespan.

## Contribution

A practical methodology for evaluating polymer cable insulation lifespan under thermo-oxidative conditions is proposed.

## Key findings

- PPG cables have an estimated lifespan of 45.65 years at 110 °C, outperforming XLPE at 37.75 years at 90 °C.
- The study identifies the most sensitive parameter for tracking insulation ageing during thermo-oxidative experiments.
- Sample thickness significantly influences the insulation ageing process.

## Abstract

Grafted polypropylene (PPG) has demonstrated significant potential as a recyclable insulation material for high-voltage cables. While its fundamental electrical, mechanical and thermal properties have been widely studied, research on its long-term performance remains insufficient. This study comparatively investigates the thermo-oxidative ageing performance of PPG and traditional cross-linked polyethylene (XLPE) to evaluate the expected lifespan of cable insulation. The evolution of mechanical and electrical properties of PPG and XLPE was monitored during accelerated thermo-oxidative ageing experiments conducted at their respective maximum allowable operating temperatures, and the most sensitive ageing parameter was identified. Furthermore, the influence of thickness on the insulation ageing process was examined through experiments on samples of different thicknesses. Results indicate that the estimated thermo-oxidative ageing lifespan of XLPE at its maximum operating temperatures of 90 °C is 37.75 years, while that of PPG at 110 °C is 45.65 years. This work offers a practical methodology for polymer ageing lifespan analysis and provides valuable insights for assessing the long-term performance of PPG cables in high-voltage applications.

## Full-text entities

- **Chemicals:** polymer (MESH:D011108), Polypropylene (MESH:D011126), PPG (-)

## Full text

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## Figures

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## References

29 references — full list in the complete paper: https://tomesphere.com/paper/PMC12899345/full.md

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Source: https://tomesphere.com/paper/PMC12899345