# Hydrothermal Conversion of Wastewater Treatment Sands into Dual-Phase FAU/LTA Zeolite: Structural Insights and Performance in Methylene Blue Adsorption

## TL;DR

This paper shows how sand from wastewater treatment plants can be turned into a useful material that removes pollutants like methylene blue from water.

## Contribution

The study introduces a novel method to convert WWTP residual sands into dual-phase FAU/LTA zeolite with high adsorption performance.

## Key findings

- ZEO-RS achieved 92% equilibrium uptake of methylene blue within 30 minutes.
- The material showed a maximum adsorption capacity of 34.2 mg/g at 20°C.
- MB adsorption was spontaneous, entropy-driven, and showed strong dye retention.

## Abstract

This study presents a sustainable valorization strategy for wastewater treatment plant (WWTP) residual sands through their hydrothermal conversion into a dual-phase FAU/LTA zeolite and evaluates its adsorption performance toward methylene blue (MB) as a model cationic contaminant. The synthesized material (ZEO-RS) exhibited a low Si/Al ratio (~1.7), well-developed FAU supercages with minor LTA domains, and high structural integrity, as confirmed by XRD, FTIR, XRF, SEM and PZC analyses. ZEO-RS demonstrated rapid adsorption kinetics, reaching approximately 92% of equilibrium uptake within 30 min and following a pseudo-second-order kinetic model (k2= 2.73 g·mg−1·h−1). Equilibrium data were best described by the Langmuir isotherm, yielding a maximum adsorption capacity of 34.2 mg·g−1 at 20 °C, with favorable separation factors (0 < rL < 1), while Freundlich fitting indicated moderate surface heterogeneity. Thermodynamic analysis revealed that MB adsorption is spontaneous (ΔG° = −11.98 to −12.56 kJ·mol−1), mildly endothermic (ΔH° = +5.26 kJ·mol−1), and entropy-driven (ΔS° = +0.059 kJ·mol−1·K−1). FTIR evidence, combined with pH-dependent behavior, indicates that adsorption proceeds via synergistic electrostatic attraction, pore confinement within FAU domains, and partial ion-exchange interactions. Desorption efficiencies conducted under mild acidic, neutral, and alkaline conditions resulted in low MB release (1–8%), indicating strong dye retention and high framework stability. Overall, the results demonstrate that WWTP residual sands are an effective and scalable low-cost precursor for producing zeolitic adsorbents, supporting their potential application in sustainable water purification and circular-economy-based wastewater treatment strategies.