# Functionalized Siloxane Coating as Protection of the Surface of Cement Composites Against Phototropic Colonization

## TL;DR

This study explores using a siloxane compound to coat cement composites, effectively reducing algal growth and maintaining structural integrity under harsh conditions.

## Contribution

The study introduces a functionalized siloxane coating that significantly inhibits algal photosynthesis and maintains cement composite strength.

## Key findings

- A 10% aqueous solution of HOL9 applied by painting reduced algal photosynthetic activity by 97.6%.
- Coating application methods and concentrations significantly affect the protective properties of cement composites.
- Painting HOL9 resulted in a 43.8% strength loss after freeze–thaw cycles, slightly higher than control samples.

## Abstract

This article presents the concept of using a functionalised siloxane compound HOL9 with amphiphilic properties as a coating for cement composites to enhance their antifouling properties against algae. The biological properties of the compound were assessed based on its ability to inhibit chlorophyll fluorescence intensity, which is used as an indicator of photosynthetic activity and biofilm development. The greatest decrease in algal photosynthetic activity was observed for a 10% aqueous solution of HOL9 applied by painting. In these conditions, the maximum chlFI value decreased by 97.6%. In addition, the impact of the protective coating containing HOL9 on the fundamental physical and mechanical characteristics of the cement composite, along with its resilience to frost cycling, was thoroughly investigated. The coating applied by immersion demonstrated a 50.7% strength loss after 150 freeze–thaw cycles, while the coating applied by painting exhibited a 43.8% loss. In comparison, the control samples experienced a 42.8% strength reduction. It has been demonstrated that the method of application, the modifier concentration, and the type of solvent can have a substantial impact on the protective properties of concrete. The most marked inhibition of algae photosynthetic activity was observed with a 10% aqueous solution applied by painting.