# Carbon-Modified Attapulgite Composite for Rapid Rhodamine B Degradation: High Adsorption Capacity and Photo-Fenton Efficiency

## TL;DR

A new composite material was created to efficiently remove and degrade a dye from water, offering a sustainable solution for wastewater treatment.

## Contribution

The carbon-modified attapulgite composite shows significantly improved adsorption and catalytic degradation of Rhodamine B.

## Key findings

- The composite achieved an adsorption capacity of 666.66 mg/g, nearly double that of unmodified variants.
- It degraded 99.8% of Rhodamine B within 20 minutes under photo-Fenton conditions.
- The composite's enhanced performance is attributed to its high surface area and surface charge.

## Abstract

A carbon-modified attapulgite composite (C-AATP@CTAB) was synthesized via the hydrothermal method using citric acid as the carbon source and cetyltrimethylammonium bromide (CTAB) as a surface modifier for efficient rhodamine B (Rh-B) removal. Carbon modification elevated the composite’s specific surface area (212 m2/g) and negative surface charge (−38.21 mV), significantly enhancing dye adsorption capacity to 666.66 mg/g—nearly double that of unmodified ATP variants (360.4–386.8 mg/g). Kinetic studies confirmed pseudo-second-order adsorption kinetics, attributed to hydrogen bonding and van der Waals interactions between Rh-B and the composite. Under photo-Fenton conditions, C-AATP@CTAB achieved 99.8% Rh-B degradation within 20 min, demonstrating superior catalytic performance in heterogeneous Fenton/photo-Fenton systems. This work establishes a low-cost, high-efficiency adsorbent-catalyst hybrid derived from low-grade attapulgite, offering promising avenues for sustainable wastewater treatment.