# Processing and Characterization of Poly(lactic acid) (PLA) Films Containing Pomegranate Peel Powder

## TL;DR

This study explores how adding pomegranate peel powder to PLA films affects their properties, finding that while it improves thermal stability, it weakens mechanical strength.

## Contribution

The study introduces pomegranate peel powder as a sustainable additive for PLA films and evaluates its impact on mechanical, thermal, and surface properties.

## Key findings

- Adding pomegranate peel powder increased thermo-oxidative stability by up to 30 °C at 3 wt.%
- Mechanical properties like tensile strength and elongation at break decreased with higher PoP content.
- Surface properties, color, and UV transmittance were significantly altered by PoP incorporation.

## Abstract

The present study analyses the changes in antioxidative behavior of biodegradable Poly(lactic acid) (PLA)-based composite films with bioactive additives derived from pomegranate peel, an abundant agricultural by-product rich in antioxidants and antimicrobials. PLA-based composites were prepared by incorporating industrial-grade pomegranate peel powder (PoP) via melt extrusion at concentrations of 1–5 percent by weight (wt.%). For mechanical characterization, the resulting films were subjected to tensile testing. Their thermal properties were further characterized using thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), dynamic oxidation induction temperature measurements (OIT), complemented by Fourier-transform infrared spectroscopy (FT-IR), color analysis, rheology, scanning electron microscopy (SEM), and UV-Vis spectroscopy. Results show that the incorporation of PoP had no significant impact on the characteristic transition temperatures (Tg, Tm, and Tc) of PLA, indicating that the thermal behavior of the polymer matrix was largely preserved. However, while the thermo-oxidative stability of PLA was improved in the presence of PoP, with a maximum at 3 wt.% of PoP, increasing the OIT by 30 °C, the mechanical performance of the composite films was adversely affected, as evidenced by decreased tensile strength and elongation at break indication embrittlement, especially for ≥3 wt.% of PoP. Significant changes were observed in the films’ surface properties, as well as in their color parameters and UV transmittance values. Consequently, while PoP offers potential bioactive functionality for use as a sustainable additive, its content must be carefully optimized to maintain an acceptable balance between functionality and mechanical integrity.