Design of a Recyclable Photoresponsive Adsorbent via Green Synthesis of Ag Nanoparticles in Porous Aromatic Frameworks for Low-Energy Desulfurization

TL;DR

A new recyclable adsorbent using silver nanoparticles and light to efficiently remove sulfur from fuels with low energy use.

Contribution

A green-synthesized photoresponsive adsorbent with low-energy regeneration for desulfurization is developed.

Findings

Silver nanoparticles in porous aromatic frameworks enable efficient thiophenic sulfur adsorption.

Light-induced photothermal conversion allows rapid desorption without heating.

Up to 48% of adsorbed sulfur is released under light irradiation.

Abstract

Based on the pressing need to develop efficient desulfurization technologies for fuel oils, this study presents a novel photoresponsive adsorbent for the removal of refractory thiophenic sulfides. Conventional hydrodesulfurization exhibits limited efficiency for such compounds, while adsorption–desorption processes often suffer from high energy consumption during regeneration. Inspired by natural stimuli-responsive systems, we designed a photothermal adsorbent by incorporating silver nanoparticles (Ag NPs) into a porous aromatic framework (PAF) via a green photoreduction method. The resulting materials, denoted as Ag(0)PBPAF-n (n = 1, 2, 3), were thoroughly characterized to confirm successful synthesis and structural integrity. The introduced Ag NPs serve as adsorption sites, enhancing uptake capacity through weak interactions with sulfur atoms in thiophenic molecules. More significantly, under light irradiation, the localized surface plasmon resonance (LSPR) of Ag NPs enables efficient photothermal conversion, triggering rapid desorption without conventional heating. Adsorption–desorption tests demonstrated that up to 48% of adsorbed thiophenic sulfur could be released upon illumination. Fixed-bed experiments further verified that light can effectively stimulate regeneration and improve energy efficiency. This work offers a promising strategy for designing recyclable adsorbents with low-energy regeneration driven by clean solar energy.

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