Progress on Suzuki–Miyaura Cross-Coupling Reactions Promoted by Palladium–Lanthanide Coordination Polymers as Catalytic Systems
Fu Ding, Ileana Dragutan, Lixin You, Yaguang Sun, Valerian Dragutan
TL;DR
This paper reviews how lanthanide-based coordination polymers work with palladium to efficiently catalyze Suzuki-Miyaura reactions.
Contribution
The paper highlights the novel use of Pd-Ln coordination polymers for catalytic cross-coupling reactions with high yields and recyclability.
Findings
Pd-Ln coordination polymers achieve >99% yields in Suzuki-Miyaura reactions under optimized conditions.
Lanthanides enhance catalytic activity and sustainability of Pd catalysts through synergistic effects.
Different lanthanides (Eu, Sm, Gd, etc.) show distinct roles in catalytic performance.
Abstract
Lanthanide coordination polymers have been developed at a fast rate during the past two decades due to their appealing applications in the modern field of materials science and emerging technologies like luminescence, magnetism, sensing, gas adsorption, and catalysis. The role of lanthanides in imparting specific properties to the coordination polymers has been fully documented in extensive studies carried out by numerous research groups. It has been shown that because lanthanide(III) ions possess a variable coordination number, they readily build two-dimensional and three-dimensional architectures with definite channels, permanent pores, and distinct surface areas. Due to their strong oxophilic propensity and hard Lewis acid character, lanthanides favor the construction of stable coordination polymers and MOF configurations by strongly binding the coordinating groups of the organic…
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Taxonomy
TopicsCatalytic Cross-Coupling Reactions · Metal-Organic Frameworks: Synthesis and Applications · Zeolite Catalysis and Synthesis