Investigation of the Hydration and Solidification Effect of Peanut Ash Cement-Based Stabilizer in Soft Clay Treatment

TL;DR

This study explores using peanut ash with cement to strengthen soft clay, improving durability and reducing cement use.

Contribution

A novel PA–cement composite stabilizer is proposed, showing enhanced strength and durability in soft clay treatment.

Findings

Specimens with 15% cement + 5% PA achieved 3.12 MPa strength, higher than 20% cement alone.

PA improves durability, with 22.76% strength reduction after five dry–wet cycles versus 31.31% for pure cement.

Pozzolanic reactivity of PA promotes later-stage hydration products like C-S-H gel and ettringite.

Abstract

To promote the sustainable utilization of agricultural solid waste, this study proposes a novel approach for reinforcing soft clay using a peanut ash (PA)–cement composite stabilizer. The unconfined compressive strength (UCS) of pure cement and PA–cement composite systems was tested at curing ages of 3, 7, and 28 days, while the durability of the stabilized clay was evaluated through dry–wet cycling. Given that PA is rich in pozzolanic components, its addition may influence the hydration process of cement. Therefore, hydration heat analysis was conducted to examine the early hydration behavior, and XRD and TG analyses were employed to identify the composition and quantity of hydration products. SEM observations were further used to characterize the microstructural evolution of the stabilized matrix. By integrating mechanical and microstructural analyses, the solidification mechanism of the PA–cement stabilizer was elucidated. Mechanical test results indicate that the reinforcing effect increases with the stabilizer dosage. Pure cement exhibited superior strength at 3 days; however, after 7 days, specimens incorporating 5% PA showed higher strength than those stabilized solely with cement. At 28 days, the UCS of the 15% cement + 5% PA specimen reached 3.12 MPa, 11.03% higher than that of the 20% cement specimen and comparable to the 25% cement specimen (3.15 MPa). After five dry–wet cycles, the strength reduction of the 15% cement + 5% PA specimen was 22.76%, compared to 31.31% for the 20% cement specimen, indicating improved durability. Microscopic analyses reveal that PA reduces hydration heat and does not participate in early hydration, leading to lower early strength. However, its pozzolanic reactivity contributes to secondary hydration at later stages, promoting the formation of additional C-S-H gel and ettringite. These hydration products fill the inter-lamellar pores of the clay and increase matrix density. Conversely, excessive PA content (≥10%) exerts a dilution effect, reducing the amount of hydration products and weakening the mechanical performance. Overall, the use of an appropriate PA dosage in combination with cement enhances both strength and durability while reducing cement consumption, providing an effective pathway for the high-value utilization of agricultural solid waste resources.

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